Electrically conductive sealing compositions based on polysulfi de oligomers

Authors

  • Zh.K. Myshyrova Kazakh National University named after Al-Farabi, Faculty of Chemistry and Chemical Technology, Almaty, Kazakhstan
  • M.I. Tulepov Kazakh National University named after Al-Farabi, Faculty of Chemistry and Chemical Technology, Almaty, Kazakhstan
  • R. Buskets School of Life Sciences, Pharmacy and Chemistry, Kingston University, Kingston upon Thames, UK

DOI:

https://doi.org/10.18321/cpc21(2)111-118

Keywords:

polysulfi des, carbon black, composite, resistivity, sealants.

Abstract

In this work, the electrical conductivity and physical and mechanical properties of composites based on liquid thiokol filled with technical carbon grade K-354 were studied. The aim of this work was to obtain an inexpensive electrically conductive composite using a thiokol matrix. It was found that the addition of carbon black to the thiokol matrix leads to a significant change in electrical conductivity, so with an increase in the content of carbon black in the composite material from 20 to 40 m.p., there was a regular decrease in the specific electrical volume resistance from 1.28×104 to 2.34×10 (Ohm×m) occurred. Using scanning electron microscopy, the structure of the surface of the composites and the distribution of particles in the composite matrix were studied. With an increase in the filler content, the packing of aggregates in the matrix becomes denser, which contributes to closer contact between carbon black particles, thereby creating conditions for the formation of electrically conductive chains. The resulting composite can be used as an electrically conductive sealing material.

References

(1). Nayeem A, Faizal Ali M, Haslinda SJ (2022) Materials Today 57:1095-1100. https://doi.org/10.1016/j.matpr.2021.09.397

(2). Sadieva KhR, Bishimbaeva GK, Umbetova ShM, Mateeva SZ, Dzhumabekova GB (2015) Production of sulfi de and polysulfi de of alkali and alkaline earth metals based on the processing of petroleum sulfur from the Tengiz deposit. Innovations for business in Russia and Kazakhstan. Proceedings of the Forum of Innovative Business Leaders of the Russian Federation and the Republic of Kazakhstan. Yekaterinburg, P.110.

(3). Kazerouni SS, Kalaee M, Sharif F (2016) Sulfur Chem 37:328–339. https://doi.org/10.1080/17415993.2016.1139114

(4). Kalaee M, Famili N, Mortezaei MJ (2010) Sulfur Chem 31:247–253. https://doi.org/10.1080/17415993.2010.499565

(5). Murthy KS, Kishore K, Mohan VK (1994) Macromolecules 27:7109–7114. https://doi.org/10.1021/ma00102a017

(6). Mahon A, Kemp TJ, Coates RJ (1998) Polym Degrad Stab 62:187–198. https://doi.org/10.1016/S0141-3910(97)00277-2

(7). Balakit AA, Smith K, El-Hiti GA (2018) J Sulfur Chem 39:182–192. https://doi.org/10.1080/17415993.2017.1413651

(8). Pirayesh A, Salami-Kalajahi M, Roghani-Mamaqani H (2019) Prog Org Coat 131:211–218. https://doi.org/10.1016/j.porgcoat.2019.02.035

(9). Zelinsky ND (1960). Collection of works. T. IV. M.: Ed. Academy of Sciences of the USSR. P.598.

(10). Tobolsky AV, Macknight UJ (1965). Polymer sulfur and related polymers, Polymer Rev. New York. P.140.

(11). Kishore K, Ganesh K (1995) Adv. Pol. Sci. 121:81.

(12). Ahmed A, Blanchard LP (1985) J. Appl. Polymer Sci. 29:1225. https://doi.org/10.1002/app.1984.070290418

(13). Smith K, El-Hiti GA, Al-Zuhairi AJ (2011) J Sulfur Chem. 32:521–531. https://doi.org/10.1080/17415993.2011.616589

(14). Song B, Wu F, Moon KS, Wong CP, (2019) Formulation and Processing of Conductive Polysulfi de Sealants for Automotive and Aerospace Applications. Electronic Components and Technology Conference, P.157-162. https://doi.org/10.1109/ECTC.2019.00031

(15). Wang X, Jin T, Wang HW, Liao SZ, Yang HY (2018) Chemical Journal of Chinese Universities 39:397–404. https://doi.org/10.7503/cjcu20170417

(16). Tupciauskas R, Irbe I, Janberga A, Buksans E (2017) Wood Mat Sci Eng. 12:63–71. https://doi.org/10.1080/17480272.2015.1022876

(17). Tao W, Zeng Sh, Xu Y, Nie W, Zhou Yi, Qin P, Wu S, Chen (2021) Composites Part A: Applied Science and Manufacturing 143:106293. https://doi.org/10.1016/j.compositesa.2021.106293

(18). Li X, Nie W, Xu Y, Zhou Y, Chen P, Zhang Ch (2020) Compos. B: Eng. 198:108234. https://doi.org/10.1016/j.compositesb.2020.108234

(19). Slobodkina KN, Makarov TV, Wolfson SI (2015) Bulletin of the Kazan Technological University 17:104-106. (in Russian)

(20). Khakimullin YuN, Kurbangaleeva AR, Dresvyannikov AF, Petrova EV (2012) Bulletin of the Kazan Technological University 3:47–49. (in Russian)

(21). Hadavand BS, Pishvaei M, Hosseininiasari M (2019) Progress in Organic Coatings 131:60-66. https://doi.org/10.1016/j.porgcoat.2019.02.024

(22). Apukhtina NP, Bychkova SA, Galimzyanov RF, Grunkina AD, Egorov LB (2007) Method for obtaining liquid thiokols. Patent of the Russian Federation No1840614.IPC C08G 75/16

(23). Salame I, Bandosz T, (2001) Journal of Сolloid and Interface Science 240:252-258. https://doi.org/10.1006/jcis.2001.7596

(24). ASTM D 3849-04. “Test Method for Carbon Black: Morphological Characterization of Carbon Black Using Electron Microscopy” Book of Standards, 9, 2007.

(25). Moniruzzaman M, Winey KI, (2006) Macromolecules 39:5194–5205. https://doi.org/10.1021/ma060733p

(26). Chen X, Chen X, Lin M, (2007) Macromol Chem Phys 208:964–972. https://doi.org/10.1002/macp.200600593

(27). Nasrabadi H, Kalaee M, Mazinani S (2014) Polym Plast Technol Eng 53:767–774. https://doi.org/10.1080/03602559.2014.886039

Published

2023-08-25

How to Cite

Myshyrova, Z., Tulepov, M., & Buskets, R. (2023). Electrically conductive sealing compositions based on polysulfi de oligomers. Combustion and Plasma Chemistry, 21(2), 111–118. https://doi.org/10.18321/cpc21(2)111-118

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