Адиабаталық қысу жағдайында метанның ішінара тотығуы (шолу)
DOI:
https://doi.org/10.18321/cpc24(2)137-150Кілт сөздер:
адиабатикалық қысу, химиялық қысу реакторы, парциалды тотығу, метан, синтез газы, формальдегид, метанолАңдатпа
Бос поршеньді адиабаталық газды қысу-реактор қабырғаларының әсерінсіз термиялық реакцияларды зерттеуге арналған газ фазалық кинетика әдісі. Мақалада осы әдістің артықшылықтары мен ерекшеліктері және оның технологиялық процестерде қолданылуы қарастырылады. Тарихи контексте мақалада метан қоспаларының синтез-газға және құрамында оттегі бар органикалық заттарға парциалды тотығуының адиабаталық қысу реакторында алынған эксперименттік нәтижелері келтірілген. Метанның синтез-газға каталитикалық емес конверсиясы зертханалық масштабта зерттелді және кеңейтілген қондырғыларда (химиялық сығымдау реакторлары) сыналды және практикалық қолдану үшін перспективалы деп танылды. Сондай-ақ, адиабаталық қысуды қолданған кезде формальдегид пен метанолдың іс жүзінде маңызды шығымдылығын алу мүмкін емес екендігі көрсетілген. Метанның бай қоспаларын сығу кезінде тұтану қысу коэффициенттерінің тар интервалында жүретіні, метан мен оттегінің конверсия дәрежесі күрт өсетіні анықталды. Адиабаталық қысу кезінде биогаздың модельдік қоспалары СО2 қоспаларының метанның ішінара тотығуына әсерін қарастырады. Бастапқы қоспада СО2 болуы тұтанудың қиындауына, метан мен оттегінің конверсия дәрежесінің төмендеуіне әкелетіні анықталды. СО2 үшін қысу дәрежесіне және сәйкесінше температураға байланысты үш режимнің болуы анықталды: тұтанусыз ішінара тотығу кезінде оның құрамының бастапқы деңгейге қатысты жоғарылауы, тұтану кезінде оның құрамының жоғарылауы және тұтану кезінде мазмұнның төмендеуі. Биогаздың ішінара тотығуымен H2/Co ≈ 1 қатынасымен синтез газын алуға болатындығы көрсетілген.
Әдебиеттер тізімі
(1) H. Hiller, R. Reimert, F. Marschner, H.-J. Renner, W. Boll, et al. Gas Production: in Ullman’s Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
(2) J.R. Rostrup-Nielsen. Catalysis and large-scale conversion of natural gas. Catalysis Today 21 (1994) 257-267. Crossref
(3) D.J. Wilhelm, D.R. Simbeck, A.D. Karp, R.L. Dickenson. Syngas production for gas-to-liquids applications: technologies, issues and outlook. Fuel Processing Technology 71 (2001) 139-148. Crossref
(4) V.S. Arutyunov. Oxidative Conversion of Natural Gas. KRASAND, Moscow, 2011. (In Russ.).
(5) Yu.A. Kolbanovskii, I.V. Bilera, I.V. Rossikhin, A.A. Borisov, K.Ya. Troshin. Single-stage conversion of associated petroleum gas and natural gas to syngas in combustion and auto-ignition processes. Russian Journal of General Chemistry 81 (2011) 2594-2603. Crossref
(6) M. Corke. GTL Technologies Focus on Lowering Costs. Oil and Gas Journal 96 (1998) 71.
(7) V.S. Arutyunov, A.L. Lapidus. Gas chemistry as a key area of development of energy chemical technologies of the 21st century. Russian Chemical Journal 47 (2003) 23-32. (In Russ.).
(8) O.B. Braginskii. Global petrochemical industry. Nauka, Moscow, 2003 (In Russ.).
(9) V.S. Arutyunov, V.Ya. Basevich, V.I. Vedeneev. Direct high-pressure gas-phase oxidation of natural gas to methanol and other oxygenates. Russian Chemical Review 65 (1996) 197-224. Crossref
(10) V.S. Arutyunov, V.M. Shmelev, M.Yu. Sinev, O.V. Shapovalova. Syngas and hydrogen production in a volumetric radiant burner. Chemical Engineering Journal 176-177 (2011) 291-294. Crossref
(11) V.S. Arutyunov, R.N. Magomedov. Gas-phase oxypyrolysis of light alkanes. Russian Chemical Review 81 (2012) 790-822. Crossref
(12) O.V. Shapovalova, Y.N. Chun, M.S. Lim, V.M. Shmelev, V.S. Arutyunov. Syngas and hydrogen production from biogas in volumetric (3D) matrix reformers. International Journal of Hydrogen Energy 37 (2012) 14040-14046. Crossref
(13) V.S. Arutyunov, V.I. Savchenko, I.V. Sedov, A.V. Nikitin, R.N. Magomedov, et al. Proshina. Kinetic features and industrial prospects of the selective oxidative cracking of light alkanes. Russian Chemical Review 86 (2017) 47-74. Crossref
(14) A. Nikitin, A. Ozersky, V. Savchenko, I. Sedov, V. Shmelev, et al. Matrix conversion of natural gas to syngas: The main parameters of the process and possible applications. Chemical Engineering Journal 377 (2019) 120883. Crossref
(15) V.S. Arutyunov, K.Ya. Troshin, A.A. Belyaev, A.V. Arutyunov, A.V. Nikitin, et al. Influence of the composition of gas mixtures on their self-ignition delay and normal flame. Combustion and Plasma Chemistry 18 (2020) 61-80. Crossref
(16) V.I. Savchenko, A.V. Nikitin, Y.S. Zimin, A.V. Ozerskii, I.V. Sedov, et al. Impact of post-flame processes on the hydrogen yield in partial oxidation of methane in the matrix reformer. Chemical Engineering Research and Design 175 (2021) 250-258 Crossref
(17) R.W. Haywood. Equilibrium Thermodynamics. Wiley, New York, 1980.
(18) Y.A. Kolbanovskiy, V.S. Shchipachev, N.Y. Chernyak, A.S. Chernyshova, A.S. Grigor’ev. Impulsive Compression of Gases in Chemistry and Technology. Nauka, Moscow, 1982 (In Russ.).
(19) Y.A Kolbanovskiy. Adiabatic compression in studies on the kinetics and mechanism of reactions involving fluorine-containing carbenes. Russian Chemical Review 58 (1989) 1024-1032. Crossref
(20) I.V. Bilera. The Formation of Small Amounts of Cyclopropane during Pulsed Pyrolysis of C4–C5 Acyclic Alkanes in the Adiabatic Compression Reactor. Reactions 4 (2023) 381-397. Crossref
(21) E.S. Verem’ev, V.V. Kislykh, A.E. Sidel’nikov. Investigation of the decomposition of nitrous oxide at pressures of 1500-2000 atm. Kinetics and catalysis 13 (1972) 269-273. (In Russ.).
(22) K.G. Falk. The ignition temperatures of hydrogen-oxygen mixtures. Journal of the American Chemical Society 28 (1906) 1517-1534. Crossref
(23) K.G. Falk. The ignition temperatures of gaseous mixtures. Journal of the American Chemical Society 29 (1907) 1536-1557. Crossref
(24) Y.A. Kolbanovskiy, A.M. Markevich, Khariton’s work on strong adiabatic compression of gases and their application in modern chemical kinetics and technology – Issues of modern experimental and theoretical physics. Nauka, Leningrad, 1984. (In Russ.).
(25) Yu.N. Ryabinin. Gases at High Densities and Temperatures. Pergamon Press, New York, 1961.
(26) A.M. Markevich, V.V. Azatyan, N.A. Sokolova. Adiabatic compression as a method for studying chemical processes under nonstationary conditions. Kinetics and catalysis 3 (1962) 431-438. (In Russ.).
(27) I.E. Volokhonovich, A.M. Markevich, I.F. Masterovoy, V.V. Azatyan. Non-isothermal processes. Thermal cracking of methane. Doklady USSR 146 (1962) 387-390. (In Russ.).
(28) V.N. Kondratiev. Determination of the rate constant for thermal cracking of methane by means of adiabatic compression and expansion. Symposium (International) on Combustion 10 (1965) 319-322. Crossref
(29) G.G. Torchan, A.A. Mantashyan, A.B. Nalbandyan. Methane oxidation under conditions of adiabatic compression. Chemical Journal of Armenia 27 (1974) 271-278. (In Russ.).
(30) G.G. Torchan, A.A. Mantashyan, A.B. Nalbandyan. Effect of reagent concentration on methane oxidation reaction under adiabatic compression conditions. Chemical Journal of Armenia 28 (1975) 443-450. (In Russ.).
(31) G.G. Torchan, Yu.S. Grigoryan, A.A. Mantashyan, A.B. Nalbandyan. Oxidative cracking of methane under conditions of adiabatic compression. Chemical Journal of Armenia 28 (1975) 857-861. (In Russ.).
(32) G.B. Barannik, V.S. Babkin. Decomposition of formaldehyde under adiabatic compression in the presence of oxygen. Combustion Explosion and Shock Waves 9 (1973) 363-366. Crossref
(33) I.V. Bilera. Copyrolysis of dimethyl ether and methane under pulsed adiabatic compression. Gorenie i vzryv. (Mosk.) – Combustion and explosion 12 (2019) 34-41. (In Russ.). Crossref
(34) I.V. Bilera. Oxidative pyrolysis of ethane under pulsed adiabatic compression. Gorenie i vzryv. (Mosk.) – Combustion and explosion 16 (2023) 21-29. (In Russ.). Crossref
(35) I.V. Bilera. Effect of hydrogen addition on oxidative pyrolysis of ethane under adiabatic compression conditions. Gorenie i vzryv. (Mosk.) – Combustion and explosion 17 (2024) 40-48. (In Russ.). Crossref
(36) I.V. Bilera. Ignition of model biogas mixtures in an adiabatic compression reactor. Gorenie i vzryv. (Mosk.) – Combustion and explosion 18 (2025) 34-44. (In Russ.). Crossref
(37) I.V. Bilera. Partial oxidation of biogas–simulating CH4–CO2 mixtures under adiabatic compression conditions. Russian Journal of Physical Chemistry B 19 (2025) 589-597. Crossref
(38) A. Ashok, M.A. Katebah, P. Linke, D. Kumar, D. Arora, et al. Review of piston reactors for the production of chemicals. Reviews in Chemical Engineering 39 (2023) 1-30. Crossref
(39) M.H. McMillian, S.A. Lawson. Experimental and modeling study of hydrogen/syngas production and particulate emissions from a natural gas-fueled partial oxidation engine. International Journal of Hydrogen Energy 31 (7) (2006) 847-860. Crossref
(40) G.A. Karim, I. Wierzba. The production of hydrogen through the uncatalyzed partial oxidation of methane in an internal combustion engine. International Journal of Hydrogen Energy 33 (2008) 2105-2110. Crossref
(41) Y.C. Yang, M.S. Lim, Y.N. Chun. The syngas production by partial oxidation using a homogeneous charge compression ignition engine. Fuel Processing Technology 90 (2009) 553-557. Crossref
(42) E.G. Lim, E.E. Dames, K.D. Cedrone, A.J. Acocella, T.R. Needham, et al. The engine reformer: Syngas production in an engine for compact gas-to-liquids synthesis. Canadian Journal of Chemical Engineering 94 (2016) 623-635. Crossref
(43) S. Wiemann, R. Hegner, B. Atakan, C. Schulz, S.A. Kaiser. Combined production of power and syngas in an internal combustion engine – Experiments and simulations in SI and HCCI mode. Fuel 215 (2018) 40-45. Crossref
(44) P. Mishra, H. Gossler, O. Deutschmann. Optimization of operating conditions of an internal combustion engine used as chemical reactor for methane reforming using ozone as an additive. Applications in Energy and Combustion Science 13 (2023) 100109. Crossref
(45) K. Banke, D. Freund, B. Atakan, S.A. Kaiser. Evaluation of fuel additives for HCCI engines operated on fuel-rich methane/air mixtures: DME, DEE, and n-heptane. Applications in Energy and Combustion Science 13 (2023) 100112. Crossref
(46) M. Lemke, C. Rudolph, B. Atakan, J. Reiss. Evaluation and optimization of H2 and C2H4 production in piston engines via an adjoint-based approach. Applications in Energy and Combustion Science 14 (2023) 100120. Crossref
(47) A. Egerton, N.P.W. Moore, W.T. Lyn. Ignition of Methane – Air Mixtures by Rapid Compression. Nature 167 (1951) 191-192. Crossref
(48) N.P.W. Moore, J.R. Simonson. Ignition of Methane – Air Mixtures by Rapid Compression. Nature 173 (1954) 543-544. Crossref
(49) A.G. Gaydon, N.P.W. Moore, J.R. Simonson. Chemical and Spectroscopic Studies of Blue Flames in the Auto-Ignition of Methane. Proceedings of the Royal Society A 230 (1955) 1-19. Crossref
(50) V.Ya. Basevich, S.M. Frolov. Kinetics of ′blue’ flames in the gas-phase oxidation and combustion of hydrocarbons and their derivatives. Russian Chemical Review 76 (2007) 867-884. Crossref
(51) A.M. Markevich, I.I. Tamm, Yu.N. Ryabinin. Production of formaldehyde in the adiabatic compression of methane-oxygen mixtures. Russian Journal of Physical Chemistry 32 (1958) 2241-2245. (In Russ.).
(52) P.E. Oberdorfer, R.F. Winch. Chemicals from methane in a high compression engine. Industrial and Engineering Chemistry. 53 (1961) 41-44. Crossref
(53) A.S. Grigoriev, Y.A. Kolbanovsky, V.S. Shchipachev. Oxidation of methane at adiabatic compression of its mixture with oxygen. Petroleum Chemistry U.S.S.R. 17 (1977) 64-75. Crossref
(54) V.G. Sister, A.A. Borisov, K.Ya. Troshin, I.V. Bilera, V.A. Bogdnov, et al. Partial oxidation of methane in burning and spontaneous combustion modes. Khimicheskaya Fizika 25 (2006) 61-68. (In Russ.).
(55) I.V. Bilera, V.A. Bogdanov, A.A. Borisov, Yu.A. Kolbanovskii, G.G. Politenkova, et al. Physicochemical peculiarities of partial oxidation of methane in the self-ignition regime – Nonequilibrium processes. Plasma, Combustion and Atmospheric phenomena. Ed. G.D. Roy, S.M. Frolov, A.M. Starik. Torus Press, Moscow, 2007. Р. 37-38.
(56) I.V. Bilera, A.A. Borisov, A.B. Borunova, Yu.A. Kolbanovskiii, Yu.M. Korolev, et al. Manufacture of Synthesis Gas by the Methane Combustion Process: The Formation of Soot and Its Physicochemical Characteristics. Petroleum Chemistry 50 (2010) 338-343. Crossref
(57) Yu.A. Kolbanovskiii, N.A. Plate. Power Units in Chemical Engineering. Petroleum Chemistry 40 (2000) 289-298.
(58) Yu.A. Kolbanovskiii. Some Problems of Designing Environmentally Clean Fuels for Spark-Ignition Engines. Petroleum Chemistry 42 (2002) 154-159.
(59) L. von Szeszich. Herstellung von Synthesegas im Otto-Motor bei gleichzeitiger Arbeitsgewinnung. Chemie Ingenieur Technik 28 (1956) 190-195. Crossref
(60) N.I. Kobozev, Ya.S. Kazarnovskii, I.I. Mendelevich. Explosive methane conversion – Chemical processing of petroleum hydrocarbons. Publishing House of the USSR Academy of Sciences, Moscow, 1956. P. 133-166 (In Russ.).
(61) M. Katebah, A. Abousrafa, M. Al-Rawashdeh, P. Linke. Hydrogen production using piston reactor technology: Process design and integration for CO2 emission reduction. Energy 259 (2022) 124999. Crossref
(62) A. Abousrafa, M.A. Katebah, P. Linke, T. Jacobs, M. Al-Rawashdeh. Model-based evaluation of piston reactor to produce hydrogen from methane via gas-phase SMR and ATR routes. Energy Conversion and Management 321 (2024) 119036. Crossref
(63) C. Rudolph, B. Atakan. Dry Methane Reforming in a Piston Engine for Chemical Energy Storage and Carbon Dioxide Utilization: Kinetic Modeling and Thermodynamic Evaluation. Energy Technology 11 (2023) 2201252. Crossref
Жүктеулер
Жарияланды
Журналдың саны
Бөлім
Лицензия
Авторлық құқық (c) 2026 И.В. Билера
Бұл жұмыс Creative Commons атрибуты бойынша лицензияланған. 4.0 Халықаралық лицензия.
Дәйексөзді қалай келтіруге болады
