Li+–Zn2+ гибридті электролиттердің ZnǁLiFePO4 сулы аккумуляторларының коррозиясын басуына және электрохимиялық өнімділігіне синергетикалық әсерлері
DOI:
https://doi.org/10.18321/cpc23(4)467-479Кілт сөздер:
сулы мырыш-иондық аккумуляторлар, дендриттер, литий темір фосфаты, гибридті электролит, Zn анод, анодтық еру, гальваникалық тұндыруАңдатпа
Сулы мырыш-иондық батареялар (AZIBs) қауіпсіз және тұрақты энергияны сақтау үшін ерекше маңызды болып табылады. Дегенмен, мырыш анодының тұрақсыздығы, дендриттің түзілуі, сутегінің бөлінуі, коррозияның болуы ұзақ мерзімді өнімділікті шектейді. Бұл зерттеу Zn2+ және Li+ иондарының қатынасы әртүрлі гибридті электролиттерді зерттейді. 1 M ZnSO4 + 1 M Li2SO4 электролиті коррозияға қарсы токтың ең төменгі тығыздығын (0,00026 мА·см-2) тудыра отырып, заряд тасымалдау кедергісін төмендетті (Rct = 8,91 Ом) және тұрақты цикл өнімділігін (50 циклден астам 135-158 мАч/г) көрсетті. Электрохимиялық және морфологиялық талдаулар біркелкі, дендриттерсіз Zn шөгіндісін растады. Бұл нәтижелер AZIB өнімділігін арттырудағы Li+–Zn2+ гибридті электролиттерінің синергиялық әсерін көрсетеді.
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