Production of electrodes based on porous graphene-like carbon from biomass for supercapacitors with high-performance

Authors

  • A.N. Duisenbek Satbayev University, 22a Satpayev str., Almaty, Kazakhstan; Institute of Combustion Problems, 172 Bogenbay Batyr Str., Almaty, Kazakhstan
  • E.E. Beissenova Satbayev University, 22a Satpayev str., Almaty, Kazakhstan; Institute of Combustion Problems, 172 Bogenbay Batyr Str., Almaty, Kazakhstan
  • K. Askaruly Satbayev University, 22a Satpayev str., Almaty, Kazakhstan; Institute of Combustion Problems, 172 Bogenbay Batyr Str., Almaty, Kazakhstan; G. Daukeev Almaty University of Energy and Communications, 126/1, Baitursynov str., Almaty, Kazakhstan
  • R.E. Beissenov Kazakh-British Technical University, 59 Tole bi str., Almaty, Kazakhstan; Institute of Combustion Problems, 172 Bogenbay Batyr Str., Almaty, Kazakhstan
  • Kudaibergenov A.D. Satbayev University, 22a Satpayev str., Almaty, Kazakhstan; Institute of Combustion Problems, 172 Bogenbay Batyr Str., Almaty, Kazakhstan
  • S. Tursyntai Satbayev University, 22a Satpayev str., Almaty, Kazakhstan; Institute of Combustion Problems, 172 Bogenbay Batyr Str., Almaty, Kazakhstan
  • N.G. Prikhodko Institute of Combustion Problems, 172 Bogenbay Batyr Str., Almaty, Kazakhstan; G. Daukeev Almaty University of Energy and Communications, 126/1, Baitursynov str., Almaty, Kazakhstan

Keywords:

biomass, electrode, graphene-like carbon, supercapacitor, carbonization, activation, graphene

Abstract

This article presents the synthesis of graphene-like carbon (GLC) from coffee waste (CW) for use as a precursor of electrode materials for energy storage devices. It was also synthesized by pre-carbonation at 550 °C and thermochemical activation in KOH at 850 °C in a tube furnace. SEM, BET, and Raman spectroscopy studied the structure and morphology of the resulting GLC-CW sample. Raman spectroscopic analysis confirmed the formation of multilayer graphene with numerous structural defects. Voltammetric and electrochemical characterization of the sample was carried out using a potentiostat-galvanostat. Also, GPU-CW showed a high specific surface area of 2136 m2 g-1 according to the Brunauer-Emmett-Teller (BET) method. The synthesized GLC-CW powder was used as the active material in assembling a double-layer electrochemical capacitor. The electrochemical characteristics of the assembled capacitors showed a specific capacitance value of 223 F/g at a current density of 0.5 A/g, as well as high cyclic stability with capacity retention of at least 95% after 5000 cycles. The results indicate that graphene-like carbon from coffee waste is a promising material for creating high-voltage supercapacitors.

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Published

2024-06-17

How to Cite

Duisenbek, A., Beissenova, E., Askaruly, K., Beissenov, R., A.D. , K., Tursyntai, S., & Prikhodko, N. (2024). Production of electrodes based on porous graphene-like carbon from biomass for supercapacitors with high-performance. Combustion and Plasma Chemistry, 22(2), 91–98. Retrieved from https://cpc-journal.kz/index.php/cpcj/article/view/434

Issue

Vol. 22 No. 2 (2024): COMBUSTION AND PLASMACHEMISTRY

Section

Статьи

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