Synthesis of nanofi brous hybrid composite from carbamide treated oxidized carbon obtained via К2СО3 activation of carbonized lignocellulose

Authors

  • J.M Jandosov Institute of Combustion Problems, 172 Bogenbay batyr str., Almaty, Kazakhstan; Al-Farabi Kazakh National University, 71, Al-Farabi ave., Almaty, Kazakhstan
  • A.Zh. Baimenov Institute of Combustion Problems, 172 Bogenbay batyr str., Almaty, Kazakhstan; National Laboratory Astana, Nazarbayev University, 53, Kabanbay batyr ave., Astana, Kazakhstan
  • S. Azat Institute of Combustion Problems, 172 Bogenbay batyr str., Almaty, Kazakhstan; Laboratory of Engineering Profile, Satbayev University, 22a Satpayev str., Almaty, Kazakhstan
  • Sh. Sultakhan Institute of Combustion Problems, 172 Bogenbay batyr str., Almaty, Kazakhstan; Al-Farabi Kazakh National University, 71, Al-Farabi ave., Almaty, Kazakhstan;
  • R.G. Abdulkarimova Institute of Combustion Problems, 172 Bogenbay batyr str., Almaty, Kazakhstan; Al-Farabi Kazakh National University, 71, Al-Farabi ave., Almaty, Kazakhstan
  • B.Т. Lesbaev Institute of Combustion Problems, 172 Bogenbay batyr str., Almaty, Kazakhstan; Al-Farabi Kazakh National University, 71, Al-Farabi ave., Almaty, Kazakhstan
  • Ye.О. Doszhanov Institute of Combustion Problems, 172 Bogenbay batyr str., Almaty, Kazakhstan; Al-Farabi Kazakh National University, 71, Al-Farabi ave., Almaty, Kazakhstan
  • Z.А. Mansurov Institute of Combustion Problems, 172 Bogenbay batyr str., Almaty, Kazakhstan; Al-Farabi Kazakh National University, 71, Al-Farabi ave., Almaty, Kazakhstan

DOI:

https://doi.org/10.18321/cpc21(4)273-285

Keywords:

carbon nanofiber, pyrolysis, carbamide, functionalization, N-rich activated carbon

Abstract

In this study, bamboo-like carbon nanofiber (CNF) supported with powdered N-functionalized active carbon (AC) were obtained using conventional methods, e.g.: carbonization of rice husk in a rotary steel reactor followed by potassium carbonate activation, water washing, nitric acid oxidation, carbamide impregnation and finally annealing in Ar flow at 950 ºС in quartz tube reactor. Along the course of retracting the tube from the furnace, resublimation of carbamide pyrolysis products took place leading to the AC/CNF composite formation. Physicochemical properties of the achieved material were investigated by different methods, inclusive of low-temperature nitrogen adsorption, XPS, SEM/EDS, as well as TEM. The nitrogen adsorption results showed that micro-mesoporous material with high surface area and large pore volume was obtained, the results for XPS and EDS revealed that obtained composite contains appreciable amount of covalently bound nitrogen in AC part (up to1.4 %), while on SEM and TEM images, bamboo-like CNF within size range of 90-3000 nm are clearly seen, some of them tipped with iron carbide microparticles. Our results proposed a facile one-pot synthesis of N-rich AC/nanofibrous hybrid composite from oxidized AC and carbamide, with potential applications, such as electrode material for electrochemical applications, advanced carbon adsorbents and catalysts for various processes.

References

(1). Zhuravsky SV, Kartel MT, Tarasenko YO, Villar-Rodil S, Dobos G, Tóth A, Tascón JMD, László K (2012) Applied Surface Science 258(7): 2410–2415. https://doi.org/10.1016/j.apsusc.2011.10.062

(2). Seredych M, Hulicova-Jurcakova D, Lu GQ, Bandosz TJ (2008) Carbon 46(11):1475–1488. https://doi.org/10.1016/j.carbon.2008.06.027

(3). Jandosov JM, Mikhalovska LI, Howell CA, Chenchik DI, Kosher BK, Lyubchik SB, Silvestre-Albero J, Ablaikhanova NT, Srailova GT, Tuleukhanov ST, Mikhalovsky SV (2017) Eurasian Chemico-Technological Journal 19(4):303–313. https://doi.org/10.18321/ectj678

(4). Satayeva AR, Howell CA, Korobeinyk AV, Jandosov J, Inglezakis VJ, Mansurov ZA, Mikhalovsky SV (2018) Science of The Total Environment 630(15):1237–1245. https://doi.org/10.1016/j.scitotenv.2018.02.329

(5). Merkel A, Satayeva A, Cannon F, Howell C, Meikle St, László K, Inglezakis V, Jandosov J, Ray S, Mansurov ZA, Mikhalovsky S (2016) Eurasian Chemico-Technological Journal 18(4):299–304. http://doi.org/10.18321/ectj472

(6). Schaber PM, Colson J, Higgins S, Thielen D, Anspach B, Brauer J (2004) Thermochimica Acta. 424(1-2):131–142. https://doi.org/10.1016/j.tca.2004.05.018

(7). Back RA, Childs J (1968) Canadian Journal of Chemistry 46(6):1023–1024. https://doi.org/10.1139/v68-166

(8). Thomas A, Fischer A, Goettmann F, Antonietti M, Muller J.O, Schlo¨gl R, Carlsson JM (2008) Journal of Materials Chemistry 18:4893–4908. https://doi.org/10.1039/B800274F

(9). Terrones M, Grobert N, Terrones H (2002) Carbon 40(10):1665–1684. https://doi.org/10.1016/S0008-6223(02)00008-8.

(10). Liu H, Zhang Y, Li R, Sun X, Désilets S, Abou-Rachid H, Jaidann M, Lussier LS (2010) Carbon 48(5):1498–1507. https://doi.org/10.1016/j.carbon.2009.12.045

(11). Jia Z, Kou K, Qin M, Wu H, Puleo F, Leonarda FL (2017) Catalysts 7:256. https://doi.org/10.3390/catal7090256

(12). Ashok A, Kumar A, Ponraj J, Mansour SA (2020) Carbon 170:452–463. https://doi.org/10.1016/j.carbon.2020.08.047

(13). Hessels CJM, Homan TAM, Deen NG, Tang Y (2022) Powder Technology 407:117540. https://doi.org/10.1016/j.powtec.2022.117540

(14). Steinbach I, Plapp M (2012) Continuum Mechanics and Thermodynamics 24:665–673. https://doi.org/10.1007/s00161-011-0204-y

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Published

2023-12-26

How to Cite

Jandosov , J., Baimenov, A., Azat, S., Sultakhan, S., Abdulkarimova, R., Lesbaev, B., Doszhanov, Y., & Mansurov, Z. (2023). Synthesis of nanofi brous hybrid composite from carbamide treated oxidized carbon obtained via К2СО3 activation of carbonized lignocellulose. Combustion and Plasma Chemistry, 21(4), 273–285. https://doi.org/10.18321/cpc21(4)273-285

Issue

Vol. 21 No. 4 (2023): COMBUSTION AND PLASMACHEMISTRY

Section

Статьи

License

Copyright (c) 2023 Ж.М. Жандосов, А.Ж. Байменов, С. Азат, Ш. Султахан, Р.Г. Абдулкаримова, Б.Т. Лесбаев, Е.О. Досжанов, З.А. Мансуров

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