Effect of Ti3C2(MXene) additives on the combustion of ammonium perchlorate
DOI:
https://doi.org/10.18321/cpc21(4)257-263Keywords:
Mxene, catalyst, energy, ammonium perchlorate, thermal decomposition.Abstract
This paper describes the results of a study involving the synthesis of Ti3C2 (Mxene) and its use as a catalyst for the decomposition of ammonium perchlorate (AP). Using differential scanning calorimetry (DSC) and thermogravimetric analysis (TG), the process of thermal decomposition of PCA was studied at a catalyst content of 2-10% of the total mass. The analysis results show that the presence of the Mxene catalyst significantly modifies the process of thermal decomposition of PCA. There is a decrease in energy costs to initiate the decomposition reaction, accompanied by an increase in the release of thermal energy. The increase in the amount of released energy is due to the high catalytic activity of this additive.
References
(1). Denisyuk AP, Demidova LA, Galkin VI (1995) Combustion, Explosion and Shock Waves 31:161–167. https://doi.org/10.1007/BF00755743
(2). Boldyrev VV (2006) Thermochimica Act. 443(1):1–36. https://doi.org/10.1016/j.tca.2005.11.038
(3). Dey A, Sikder AK, Talawar MB, Chottopadhyay S (2015) Cent. Eur. J. Energ. Mater. 12(2):377–399.
(4). Khan MAS, Vijayalakshmi R, Singh A, Nandi AK, Talawar MB (2019) CrystEngComm 48. https://doi.org/10.1039/C9CE01262A.
(5). Singh S, Srivastava P, Singh G (2015) Journal of Industrial and Engineering Chemistry 27:88–95. https://doi.org/10.1016/j.jiec.2014.11.047
(6). Jacobs PWM, Whitehead HM (1969) Chemical Reviews 69(4):551–590. https://doi.org/10.1021/cr60260a005
(7). Chen J, Huang B, Liu Y, Qiao Zh, Li X, Lv G, Yang G (2021) Energetic Materials Frontiers 2(1):14–21. https://doi.org/10.1016/j.enmf.2021.01.003
(8). Ye P, Xu P, Guo H, Gao B, Yang G, Huang B, Guo C (2020) Materials & Design 191:108666. https://doi.org/10.1016/j.matdes.2020.108666
(9). Jain S, Chakraborty S, Qiao L (2019) Combustion and Flame 206:282–291. https://doi.org/10.1016/j.combustflame.2019.05.004
(10). Zhang Y, Li K, Liao J, Wei X, Zhang L (2020) Applied Surface Science 499:143875. https://doi.org/10.1016/j.apsusc.2019.143875
(11). Li D, Li J, Qin L, Hu Y, Gong T, Zhang W, Hui L, Feng H (2021) Applied Surface Science 563:150207. https://doi.org/10.1016/j.apsusc.2021.150207
(12). Isert S, Xin L, Xie J, Son SF (2017) Combustion and Flame 183:322–329. https://doi.org/10.1016/j.combustflame.2017.05.024
(13). Aziz A, Mamat R, Wan Ali WK, Mohd Perang MR (2015) Applied Mechanics and Materials 773-774:470–475. https://doi.org/10.4028/www.scientific.net/AMM.773-774.470
(14). Babuk V, Dolotkazin I, Gamsov A, Glebov A, DeLuca L, Galfetti L (2009) Journal of Propulsion and Power 25(2):482–489. https://doi.org/10.2514/1.36841
(15). Tang P, Yang B, Li R, Wang Y, Li X, Yang G(2002) Carbon 186:678-687. https://doi.org/10.1016/j.carbon.2021.10.069
(16). Lu Y, Chen J, Wang R, Xu P, Zhang X, Gao B, Guo Ch, Yang G (2019) Applied Surface Science 470:269–275. https://doi.org/10.1016/j.apsusc.2018.11.108
(17). Vyazovkin S, Wight CA. (1999) Chemistry of Materials 11(11):3386–3393. https://doi.org/10.1021/cm9904382
(18). Sun X, Qiu X, Li L, Li G (2008) Inorganic Chemistry 47(10):4146–4152. https://doi.org/10.1021/ic702348c
