Perovskite catalysts for dry conversion of methane. Short review

Authors

  • N. Khudaibergenov Institute of combustion problems, Bogenbai Batyr Str., 172, Almaty, Kazakhstan
  • G. Yergaziyeva Institute of combustion problems, Bogenbay Batyr Str., 172, Almaty, Kazakhstan; Al-Farabi Kazakh National University, 71 Al-Farabi ave., Almaty, Kazakhstan
  • K. Dosumov Institute of combustion problems, Bogenbai Batyr Str., 172, Almaty, Kazakhstan
  • M. Anisova Institute of combustion problems, Bogenbay Batyr Str., 172, Almaty, Kazakhstan
  • M. Mambetova Institute of combustion problems, Bogenbay Batyr Str., 172, Almaty, Kazakhstan; Al-Farabi Kazakh National University, 71 Al-Farabi ave., Almaty, Kazakhstan
  • N. Makayeva Institute of combustion problems, Bogenbay Batyr Str., 172, Almaty, Kazakhstan; Al-Farabi Kazakh National University, 71 Al-Farabi ave., Almaty, Kazakhstan
  • K. Aliyev Al-Farabi Kazakh National University, 71 Al-Farabi ave., Almaty, Kazakhstan
  • A. Mendibay Al-Farabi Kazakh National University, 71 Al-Farabi ave., Almaty, Kazakhstan
  • M. Atamanov Institute of combustion problems, Bogenbay Batyr Str., 172, Almaty, Kazakhstan; Al-Farabi Kazakh National University, 71 Al-Farabi ave., Almaty, Kazakhstan

DOI:

https://doi.org/10.18321/cpc21(1)53-70

Keywords:

Carbon dioxide conversion of methane, perovskite catalysts, synthesis gas.

Abstract

This review analyzes modern studies of the influence of the nature of perovskite catalyst systems on dry reforming of methane (DRM) and possible ways to improve perovskite catalysts for the production of synthesis gas from two greenhouse gases (CH4 and CO2) have been discussed. It has been established that the properties and catalytic activity of perovskite Ni, Fe, Co, La containing catalysts vary depending on the synthesis method used and the presence of promoters such as ZrO2, CeO2, K2O, and MgO. It has been shown that nanostructured perovskite catalysts with dispersed active-phase metal nanoparticles are highly reactive and stable at elevated temperatures. It has been shown that LaNiO3 perovskites are highly effective DRM catalysts, and the use of La2NiO4 as a precursor leads to high catalytic activity. Perovskite SrZrRuO3 showed high activity even under extreme conditions of high space velocity, which makes them promising catalysts for DRM. Various perovskite-based catalysts exhibit high catalytic performance and long-term stability without coking. In general, it follows from the literature review that further research is needed to optimize the physicochemical characteristics of perovskite catalysts for DRM. Perovskite-based catalysts have the potential to play a significant role in reducing greenhouse gas emissions of methane and carbon dioxide.

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— Updated on 2023-03-15

How to Cite

Khudaibergenov, N., Yergaziyeva, G., Dosumov, K., Anisova, M., Mambetova, M., Makayeva, N., Aliyev, K., Mendibay, A., & Atamanov, M. (2023). Perovskite catalysts for dry conversion of methane. Short review. Combustion and Plasma Chemistry, 21(1), 53–70. https://doi.org/10.18321/cpc21(1)53-70

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Vol. 21 No. 1 (2023): COMBUSTION AND PLASMA CHEMISTRY

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