PLASMA CHEMICAL SYNTHESIS OF THIN DISPERSION POWDER OF TITANIUM DIOXIDE OF ANATASE CRYSTALLINE MODIFICATION WITH THE CHLORIDE METHOD

Authors

  • E.V. Kartaev Institute of Theoretical and Applied Mechanics behalf of S.A. Khristianovich SB RAS 630090, Novosibirsk, Institutskaya str. 4/1
  • S.M. Aulchenk Institute of Theoretical and Applied Mechanics behalf of S.A. Khristianovich SB RAS 630090, Novosibirsk, Institutskaya str. 4/1
  • V.P. Lukashov Institute of Theoretical and Applied Mechanics behalf of S.A. Khristianovich SB RAS 630090, Novosibirsk, Institutskaya str. 4/1
  • S.P. Vashchenko Institute of Theoretical and Applied Mechanics behalf of S.A. Khristianovich SB RAS 630090, Novosibirsk, Institutskaya str. 4/1
  • V.A. Emelkin Institute of Theoretical and Applied Mechanics behalf of S.A. Khristianovich SB RAS 630090, Novosibirsk, Institutskaya str. 4/1

Keywords:

plasma-chemical, dioxide-titanium, chlorine, anatase, synthesis

Abstract

The experimental investigation of the gas-phase synthesis of the nanosized particles of titanium dioxide (titania, TiO2) from gaseous titanium tetrachloride (TiCl4) in the plasmachemical flow reactor is carried out. The processes of formation and growth of particles, formation of their agglomerates in combined reaction and quenching zones are considered. The conducted experiments reveal that using this technique it is possible to produce ultrafine powder (with particle mean size less than 30 nm) providing required content of the metastable crystal lattice – 80-87% anatase (A). The content of rutile (R) crystal lattice in the powder doesn’t exceed 15-20%. The experimental data are found to agree satisfactorily with the results of simultaneously performed numerical simulations.

References

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Published

2015-04-20

How to Cite

Kartaev, E., Aulchenk, S., Lukashov, V., Vashchenko, S., & Emelkin, V. (2015). PLASMA CHEMICAL SYNTHESIS OF THIN DISPERSION POWDER OF TITANIUM DIOXIDE OF ANATASE CRYSTALLINE MODIFICATION WITH THE CHLORIDE METHOD. Combustion and Plasma Chemistry, 13(2), 154–161. Retrieved from https://cpc-journal.kz/index.php/cpcj/article/view/324

Issue

Vol. 13 No. 2 (2015): COMBUSTION AND PLASMA CHEMISTRY

Section

Статьи

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