STUDY OF THE PARAMAGNETIC CHARACTERISTICS OF GRAPHENE STRUCTURES OBTAINED IN THE GRAPHITE SYSTEM WITH AROMATIC HYDROCARBONS UNDER THE INFLUENCE OF THE ULTRASOUND FIELD

Authors

  • B.A. Baitimbetova K.I. Satpayev Kazakh national research technical university, Almaty, Kazakhstan
  • Yu.A Riabikin Institute of Physics and Technology, Almaty, Kazakhstan
  • B.A. Rahmetov Institute of Physics and Technology, Almaty, Kazakhstan
  • N. Otarova Institute of Physics and Technology, Almaty, Kazakhstan

Keywords:

graphene, aromatic hydrocarbons, ultrasonic method, EPR spectroscopy, paramagnetic centers

Abstract

This paper proposes for production of graphene to use the exposure of ultrasound field on the organic reagents and pure graphite. As organic reagents there were used kerosene, hydrogen peroxide, benzene and toluene. The paper presents experimental results of production of graphene in these systems, which is formed by a chemical reaction of these organic solvents with graphite. This leads to the destruction of the weak carbon bonds between the graphite planes. The results of this study indicate that the ultrasound field contributes to more efficient destruction of the van der Waals bonds. The use of enumerated organic solvents in contrast to other methods using acid, alkali solution provides a more efficient way to production of graphene structures. The article presents results of the study of graphene structures by electron paramagnetic resonance spectroscopy, as well as discussion is given.

References

(1) Geim A.K., Novoselov K.S. The rise of graphene. // Nature Materials. –2007. – V6 (3). – P. 183–191.

(2) Ткачев С.В., Буслаева Е.Ю., Губин С.П. Графен – новый углеродный нано- материал / Неорганические материалы. – 2011, – Том 47, – № 1, С. 5–14

(3) Андриевский Р.А. Водород в наноструктурах // Успехи физических наук, – 2007. – № – Т. 177. – №7. – С.721-735.

(4) Байтимбетова Б.А., Рябикин Ю.А. Исследование графеновых структур, образующегося при воздействии ультразвукового поля на графит. – 2015, – Вест. Казнту. Сер. технические науки.– №2. – С. 214-220.

(5) Baitimbetova B.A., Vermenichev B. M., Ryabikin Yu. A., Mansurov Z. A., Abdikasova A. A.Study of graphene formed in the atmosphere of vapors of aromatic hydrocarbons Russian Physics Journal. – 2015. – Vol. 58, – No.3, – Р.394-398. DOI 10.1007/s11182-015-0513-x.

(6) Majchrzycki M.A. Augustyniak- Jabokow R. Strzelczyk M. Makowiak A. Magnetic centers in functionalized graphene // Acta physica polonica. – 2015, – Vol. 127. – №. 2, рр. 540-542.

(7) S.S. Rao, A.Stesmans, Y.Wang, Y.Chen. Direct ESR evidence for magnetic behavior of graphite oxide // Physica E. – 2012. – P. 1036–1039.

(8) Stefan Li., Magdalena W., Stanislaw K. Hoffmann M. Electron spin relaxation and quantum localization in carbon nanoparticle: Electron spin echo studies // Physical review B – 2008. – рр.014304

(9) S. Garaj L., Thien-Nga R, Gaal L., Forro K., Takahashi F., Kokai M., Yudasak, Iijima S. Electronic properties of carbon nanohorns studied by ESR // Physical review B. – 2008. – Vol. 62, – №24. – рр.17115 17119.

(10) Srinivasa Rao, Singamaneni, Andre Stesmans, Johan van Tol. D. V. Kosynkin, James M. Tour. Magnetic defects in chemically converted graphene nanoribbons: electron spin resonance investigation // AIP advances. – 2014. – №4. – рр. 047104(11).

Published

2017-02-06

How to Cite

Baitimbetova , B., Riabikin, Y., Rahmetov , B., & Otarova, N. (2017). STUDY OF THE PARAMAGNETIC CHARACTERISTICS OF GRAPHENE STRUCTURES OBTAINED IN THE GRAPHITE SYSTEM WITH AROMATIC HYDROCARBONS UNDER THE INFLUENCE OF THE ULTRASOUND FIELD. Combustion and Plasma Chemistry, 15(1), 80–84. Retrieved from https://cpc-journal.kz/index.php/cpcj/article/view/242