SYNTHESIS OF NANO- AND MICRO PARTICLES OF CARBON BASED ON THE USE OF THE GAS-PHASE METHOD

Authors

  • M.T. Gablullin NNLОТ, al-Farabi KazNU, Almaty, Kazakhstan
  • S.А. Orazbayev NNLОТ, al-Farabi KazNU, Almaty, Kazakhstan
  • M.K. Dosbolaev NNLОТ, al-Farabi KazNU, Almaty, Kazakhstan
  • T.S. Ramazanov NNLОТ, al-Farabi KazNU, Almaty, Kazakhstan
  • D.B. Omirbekov NNLОТ, al-Farabi KazNU, Almaty, Kazakhstan

Keywords:

nanoparticles, nanomaterials, plasma, dusty gas level

Abstract

In this paper, a method for the synthesis of nano- and microparticles of carbon and the dependence of their growth on the plasma parameters have been developed and studied. Synthesis of nano- and microparticles of carbon was carried out in the plasma of a high frequency discharge in a mixture of methane gases (2%) and argon (98%) at different pressures, power and synthesis times. Based on graphical and mathematical calculations were constructed self-bias voltage dependence, and the electron density on the plasma  parameters. Also, graphs of the time dependence of the nucleation of nanoparticles on the gas temperature at different plasma parameters and the distribution of the diameter and concentration of nanoparticles on the time of synthesis in the Ar / CH4 plasma were obtained. The gas temperature ranged from 100 oC to -30 oC. It was determined that the time of formation and growth of nanoparticles increases with heating of the plasma forming gas, and with decreasing temperature it decreases.

References

(1) Merget R, Bauer T, Küpper HU, Philippou S, Bauer HD, Breitstadt R, Bruening T. Health hazards due to the inhalation of amorphous silica // Arch Toxicol. 2002 Jan;75(11-12):625-34.

(2) Erogbogbo F., Tao Lin T., Tucciarone P.M., LaJoie K.M., Lai L., Patki G.D., Prasad P.N., Swihart M.T. On-Demand Hydrogen Generation using Nanosilicon: Splitting Water without Light, Heat, or Electricity // Nano Lett., 2013, 13(2), pp 451–456. https://doi.org/10.1016/S0010-2180(99)00135-2

(3) Осипов В.В., Котов Ю.А., Иванов М.Г., Саматов О.М. Смирнов П.Б. Применение мощного импульсно-периодического СО2- лазера с высоким КПД для получения нано- размерных порошков // Изв. АН. Сер. Физическая. – 1999. – Т. 63, № 10. – С. 1968 – 1971. https://doi.org/10.1016/j.carbon.2004.05.010

(4) Andrew S. H., Mark J. F., and Brian S. M., Mechanochemical Synthesis of Blue Luminescent Alkyl/Alkenyl-Passivated Silicon Nanoparticles // WILEY-VCH VerlagGmbH&Co. KGaA, Weinheim / – Adv. Mater. – 2007, №19, – pp. 3984–3988.

(5) Ермекова Ж.С., Мансуров З.А., Мукасьян А.С. Самораспространяющийся высо- котемпературный синтез субмикронного по- рошка кремния // Горение и Плазмохимия. – 2009. – Т.7, №1. – С.1-6.

(6) Benjaram M. Reddy, Gunugunuri K. Reddy, Ibram Ganesh Jose M.F. Ferreira. Single step synthesis of nanosized CeO2–MxOy mixed oxides (MxOy = SiO2, TiO2, ZrO2, and Al2O3) by microwave induced solution combustion synthesis: characterization and CO oxidation // J. of Materials Science Letters. – 2009. – Vol. 44, № 11. – P. 2743-2751.

(7) Hiromichi H. and Yukiya H., Hydrothermal Synthesis of Metal Oxide Nanoparticles in Supercritical Water // Materials – 2010, №3, – pp. 3794-3817. https://doi.org/10.1016/S0082-0784(81)80051-3

(8) Dorothée V. S., Sabine S., Microwave Plasma Synthesis of Materials From Physics and Chemistry to Nanoparticles: A Materials Scientist’s Viewpoint// Inorganics – 2014, 2, – pp. 468- 507. https://doi.org/10.1002/bbpc.19920960702

(9) Boufendi L. and Bouchoule A. Particle nucleation and growth in a low – pressure argonsilane discharge // Plasma Sources Sci. Technol. – 1994. – Vol. 3. – P. 262.

(10) Номоев А.В., Бардаханов С.П., Синтез, строение наночастиц металл/полупроводник Ag/Si, полученных методом испарения-конденсации // Письма в ЖТФ, – 2012, том 38, вып. 8. С. 46-53.

(11) Orazbayev S.A., Ramazanov T.S., Gabdullin M.T., Dosbolayev M.K., Batryshev D.G. Synthesis of nano- and microparticles from gaseous phase in the RFCD plasma// Book of Abstracts of the 6th International Conference on Advanced Nanomaterials, (ANM). – Aveiro, Portugal, 2015. – P.110.

(12) Orazbayev S.A., Ramazanov T.S., Dosbolayev M.K., Gabdullin M.T., Batryshev D.G., Silamiya M. Synthesis of nanoparticles and nanofilms in dusty plasma for obtaining of composite materials // Book of Abstracts of the 7th International Conference on the Physics of Dusty Plasmas (ICPDP). – New Delhi, India, 2014. – P. 99. https://doi.org/10.1038/352139a0

(13) Gabdullin M.T., Orazbayev S.A., Slamia M., Batryshev D.G., Dosbolaev M.K., Ramazanov T.S., Investigation of the process of synthesis of carbon nano and microparticles in RF plasma discharge // Abstracts of the III International Scientific Conference "Modern problems of condensed matter physics, nanotechnology and nanomaterials ». – Almaty, Kazakhstan, 2014. – P. 121. (In Russian) https://doi.org/10.1016/j.proci.2004.08.238

(14) Оразбаев С.А., Рамазанов Т.С., Досболаев М.К., Батрышев Д.Г., Буфенди Л. Көміртегі нанобөлшектер синтезінің ЖЖ разряд плазмасының параметрлеріне тəуелділігін зерттеу // Журнал Известия НАН РК, серия физико-математическая. – 2015. – №3. – С. 186-190.

(15) Orazbayev S.A., Ramazanov T.S., Dosbolayev M.K., Nurbolat K. Spectroscopic diagnostics of Ar/CH4 and Ar/C2H2 gas mixtures plasma// Book of Abstracts of the 15th International Conference on the Physics of Non-Ideal Plasmas, Almaty, Kazakhstan. – 2015. – C. 121. https://doi.org/10.1016/S0008-6223(02)00276-2

(16) Ramazanov T.S., Jumabekov A.N., Orazbayev S.A., Dosbolayev M.K., and Jumagulov M.N., Optical and kinetic properties of the dusty plasma in radiofrequency discharge // Phys. Plasmas 19, 023706 (2012); doi: 10.1063/1.3690103

(17) Orazbayev S.A., Ramazanov T.S., Dosbolayev M.K., Silamiya M., Optical diagnostics of plasma in a gaseous mixture of RF discharge// Abstract Booklet of the XXII Europhysics Conference on Atomic and Molecular Physics of Ionized Gases (ESCAMPIG). - Greifswald, Germany, 2014. – P.P1-05-12. https://doi.org/10.1002/(SICI)1521-3773(19981002)37:18<2434::AID-ANIE2434>3.0.CO;2-L

(18) Orazbayev S.A., Ramazanov T.S., Dosbolayev M.K., Silamiya M., Jumagulov M.N. Spectroscopic diagnostics of plasma gas mixtures in radio frequency discharge // Book of abstracts of the 14th International Conference on the Physics of Non-Ideal Plasmas. – Rostock, Germany, 2012. – P.152. https://doi.org/10.1016/S0082-0784(96)80053-1

(19) Orazbayev S.A., DosbolayevМ.K., Silamiya M., Jumagulov M.N., Ramazanov T.S. Optical properties of the dusty plasma in RF discharge// 16thBook of abstracts of the International Congresses on Plasma Physics and 39thEuropean Physical Society Conference on Plasma Physics (EPS/ICPP). – Stockholm, Sweden, 2012. – P.2.130. https://doi.org/10.1038/nature02180

(20) Bouchoule A. and Boufendi L. Particulate formation and dusty plasma behaviour in argon-silane RF discharge // Plasma sources Sci. Technol. – 1993. – Vol. 2. – P. 204. https://doi.org/10.1039/c0cc05139j

(21) Bhandarkar U., Kortshagen U. and Girshick S. L. Numerical Study of the Effect of Gas Temperature on the Time for Onset of Particle Nucleation in Argon-Silane Low Pressure Plasmas // Journal of Physics D. – 2003. – Vol. 36. – P. 1399. https://doi.org/10.1016/j.carbon.2011.07.024

(22) Cavarroc M., Jouanny M. Ch., Radouane K., Mikikian M., Boufendi L. Self-excited instabilities occurring during the nanoparticle formation in an Ar–SiH4 low pressure radiofrequency plasma // J. Appl. Phys. – 2006. – Vol. 99. – P. 064301. https://doi.org/10.1007/978-3-642-85167-4

(23) Wattieaux G., Mezeghrane A., Boufendi L. Electrical time resolved metrology of dust particles growing in low pressure cold plasmas // Physics of Plasmas. – 2011. – Vol. 18. – P. 093701. https://doi.org/10.1007/s10891-011-0459-y

(24) Orazbayev S.A., Gabdullin M.T., Ramazanov T.S., Dosbolayev M.K., Slamiya M. The method for synthesis nanoparticles from gas phase// Book of Abstracts of the 8th International conference on Plasma Physics and Plasma Technology (PPPT). – Minsk, Belarus, 2015. – P. 490. https://doi.org/10.1134/S1990793114010059

Published

2017-02-06

How to Cite

Gablullin, M., Orazbayev, S., Dosbolaev, M., Ramazanov, T., & Omirbekov, D. (2017). SYNTHESIS OF NANO- AND MICRO PARTICLES OF CARBON BASED ON THE USE OF THE GAS-PHASE METHOD. Combustion and Plasma Chemistry, 15(1), 13–22. Retrieved from https://cpc-journal.kz/index.php/cpcj/article/view/235