Химические основы снижения пожарной опасности материалов на основе целлюлозы
Keywords:
cellulose, thermal destruction, fire hazard, dehydration, levoglucosan, fire retardants, fire protection.Abstract
The analysis of theoretical and experimental works on the study of the characteristics of the combustion process of cellulose, as well as chemical approaches and technologies to reduce the fire hazard of materials based on cellulose. The relationship between the chemical nature of cellulose and its combustibility is shown, and the possibilities of effectively reducing the fire hazard of cellulose materials are considered. The mechanisms of the fire-retardant action of various fire retardants have been analyzed. The problems and prospects of using various methods and types of fire protection for cellulose materials are discussed.
References
(1). Akim EL, Perepechkin LP (1964) Cellulose, cellulose acetate, acetate fibers [Cellyuloza, acetilcellyuloza, acetatnye volokna] Lesnaya promyshlennost’ Moscow, Russia. (in Russian)
(2). Leonovich AA (1978) Theory and practice of manufacturing fire-resistant wood-based panels [Teoriia i praktika izgotovleniia ognezashchishchennykh drevesnykh plit] Izdatelstvo Leningradskogo universiteta Leningrad, Russia. (in Russian)
(3). Baiklz N, Segal L (1974) Cellulose and its derivatives [TSelliuloza i ee proizvodnye] Vol. 2. Mir Moskva, Russia. (in Russian)
(4). Konkin AA (1978) Heat-, heat-resistant and non-combustible fibers [Termozharostoikie i negoriuchie volokna]. Chemistry, Moscow,Russia. (in Russian)
(5). Golova OP (1975) Chemical transformations of cellulose under heat exposure [Uspekhi khimii] Volume 44, 8:1454. (in Russian)
(6). Tang M, Bacon R (1964) Carbonization of cellulose fibers – I low temperature pyrolysis // Carbon, 2(3):211-220. Crossref
(7). Nikitin NI (1962) Chemistry of wood and cellulose [KHimiia drevesiny i tselliulozy] Akademiia nauk SSSR Moscow – Leningrad, Russia. [in Russian]
(8). Milosavljevic S (1975) Uticaj strukture regenerisanich celuloznik vlakana na njihovo termijsko ponasanje. Hemijska industrija 30:641-644.
(9). Domburg GE (1977) Thermal analysis of cellulose [Termicheskii analiz tselliulozy] Nauka Moscow - Leningrad, Russia. [in Russian]
(10). Shenker R, Pasku Е Chemically Modidying Cellulose for Flame Resistance // Industial and Engineering Chemistry. – 1958. – Vol. 50, №1. – P.91–96.
(11). Rogovin ZA, Galbraich LS (1979) Chemical transformations and modification of cellulose KHimiia Moscow, Russia. [in Russian]
(12). Evteev AM, Sharovarnikov AF (1993) Polymer chemistry. Fire hazard and fire protection of polymers [KHimiia polimerov Pozharnaia opasnost i ognezashchita polimerov] VIPTSH MVD RF Moskva, Russia. [in Russian]
(13). Predvoditelev DA, Nifant’ev EE, Rogovin ZA (1966) A new method for the synthesis of phosphorus-containing cellulose ethers. High molecular weight compounds 8:76-79.
(14). Predvoditelev DA, Nifantev EE, Rogovin ZA (1966) Synthesis and chemical transformations of cellulose alkylene phosphites. High molecular weight compounds 8:81-87.
(15). Rogovin ZA, Mei-yan U, Tyuganova MA, Zharova TYa, Gefter EL (1963) Synthesis of new derivatives of cellulose and other polysaccharides. XXV. Influence of the structure of organophosphate derivatives of cellulose on the fire resistance of cellulosic materials. High molecular weight compounds 4:506-511.
(16). Rogovin ZA, Mei-yan U (1963) Synthesis of new derivatives of cellulose and other polysaccharides. XXVII. Synthesis of graft copolymers of cellulose with vinyl phosphinic acid esters. High molecular weight compounds 5:706-711.
(17). Schwalbe KP (1979) Modification of wood by acetylation [Modifikaciya drevesiny putem ee acetilirovaniya] Materials of the All-Union Scientific and Technical Conference, Minsk, Belarus, P.248. [in Belarus]
(18). Makovsky YuL Fire protection of wood materials with phosphorous acid esters [оgnezashchita drevesnyh materialov efirami fosforistoj kisloty] Dissertation for the degree of candidate of technical sciences, Moscow, Russia. P.138.
(19). Berlin AlAl (1996) Combustion of polymers and polymeric materials of low flammability. Soros educational journal 9:57-63.
(20). Maksimenko NA (1985) Methods of research, research and evaluation of fire retardants used in the Senezh laboratory and their effectiveness [Metody izyskaniya, issledovaniya i ocenki antipirenov, primenyaemyh v Senezhskoj laboratorii i ih rezul’tativnost’] Collection of articles «Theoretical and practical aspects of fire protection of wood materials», Riga, Latvia, р.229. [in Latvia]
(21). Taubkin SI (1944) Methods and means of wood fire protection [Sposoby i sredstva ognezashchity drevesiny] Izdatel’stvo Narkomhoza RSFSR Moscow – Leningrad, Russia. [in Russian]
(22). Taubkin SI (1967) The basics of fire protection for cellulosic materials. [оsnovy ognezashchity tselliuloznykh materialov]. Publishing House of the Ministry of Public Utilities RSFSR. Moscow – Leningrad, Russia. [in Russian]
(23). Romanenkov IG, Siegern-Korn VN (1984) Fire resistance of building structures. [оgnestoikost stroitelnykh konstruktsii]. Stroiizdat, Moscow, Russia. [in Russian]
(24). Gorshin SN (1977) Wood preservation. [konservirovanie drevesiny]. Lesnaya promyshlennost’ Moscow, Russia. [in Russian]
(25). Leonovich AA, Shalun GB (1974) Fire protection for wood-based panels and fire-resistant plastics. [ognezashchita drevesnykh plit i ognestoikikh plastikov]. Lesnaya promyshlennost’ Moscow, Russia. [in Russian]
(26). Aseeva RM, Zaikov GE (1981) Combustion of polymer materials. [gorenie polimernykh materialov]. Nauka, Moscow, Russia [in Russian]
(27). Aseeva RM, Zaikov GE (1981) Reducing the flammability of polymeric materials. [Snizhenie goriuchesti polimernykh materialov]. Znanie, Moscow, Russia. [in Russian]
(28). Pokrovskaya EN, Nikiforova TP (1987) The problem of creating fire retardant wood materials using phosphoruscontaining compounds [Problema sozdaniia ognezashchitnykh drevesnykh materialov s pomoshchiu fosforsoderzhashchikh soedinenii] Abstracts of the II scientific-practical conference «Improvement of fire protection of wood and cellulose materials». Kiev, Ukraina, р.115. [in Ukraina]
(29). Vorobiev VA, Andrianov RA, Ushkov VA (1978) Flammability of polymer building materials [Goriuchest polimernykh stroitelnykh materialov] Stroiizdat, Moscow, Russia. [in Russian]
(30). Tyuganova MA (1985) State and prospects of scientific research in the field of obtaining fire-retardant cellulose materials [Sostoianie i perspektivy nauchnykh issledovanii v oblasti polucheniia ognezashchishchennykh tselliuloznykh materialov] Collection of articles «Theoretical and practical aspects of fire protection of wood materials» Riga, Latvia, р. 8-13. [in Latvia]
(31). Sultanov MT, Sadykov MM, Muratova UM, Tashpulatov YuT, Usmanov KhU (1986) Inhibition of combustion of cellulose with phosphorus-containing compounds. (On the inhibition of combustion in the gas phase by ammonium salts of phosphorus acids). Wood chemistry. 6:47-49.
(32). Tideman BG, Stsiborsky DB (1940) Combustion chemistry [KHimiia goreniia] Izdatel’stvo Narkomhoza RSFSR Moscow – Leningrad, Russia. [in Russian]
(34). Baratov AN, Andrianov RA, Korolchenko AYa, Mikhailov DS, Ushkov VA, Filin LG (1988) Fire hazard of building materials [Pozharnaia opasnost stroitelnykh materialov] Stroiizdat Moscow, Russia. [in Russian]
(34). Kodolov VI (1976) Flammability and fire resistance of polymeric materials [Goriuchest i ognestoikost polimernykh materialov]. KHimiia, Russia. [in Russian]
