Воздействие микроволнового нагрева на повышение выхода графена и графеноподобных структур из активированной растительной биомассы

Н.Г. Приходько; М.А. Елеуов; К. Аскарулы; Ә.Ә. Әбдiсаттар; А.Б. Толынбеков; А.Т. Таурбеков

doi:10.18321/cpc23(2)137-151

Authors

N.G. Prikhodko Institute of Combustion Problems, 172, Bogenbai Batyr str., Almaty, Kazakhstan; Almaty University of Energy and Communications named after G. Daukeev, 126/1, Baitursynov str., Almaty, Kazakhstan https://orcid.org/0000-0001-7733-0903
M.A. Yeleuov Institute of Combustion Problems, 172, Bogenbai Batyr str., Almaty, Kazakhstan; Satbayev University, 22, Satpayev str., Almaty, Kazakhstan; Bes Saiman Group, 38, Tulebayeva str., Almaty, Kazakhstan https://orcid.org/0000-0001-7488-7431
К. Askarul Institute of Combustion Problems, 172, Bogenbai Batyr str., Almaty, Kazakhstan; Almaty University of Energy and Communications named after G. Daukeev, 126/1, Baitursynov str., Almaty, Kazakhstan; Satbayev University, 22, Satpayev str., Almaty, Kazakhstan; Bes Saiman Group, 38, Tulebayeva str., Almaty, Kazakhstan https://orcid.org/0000-0002-8998-0409
A.A. Abdisattar Institute of Combustion Problems, 172, Bogenbai Batyr str., Almaty, Kazakhstan; Satbayev University, 22, Satpayev str., Almaty, Kazakhstan; Bes Saiman Group, 38, Tulebayeva str., Almaty, Kazakhstan
А.B. Tolynbekov Institute of Combustion Problems, 172, Bogenbai Batyr str., Almaty, Kazakhstan; al-Farabi Kazakh National University, 71 Al-Farabi ave., Almaty, Kazakhstan https://orcid.org/0000-0002-2664-888X
A.T. Taurbekov Institute of Combustion Problems, 172, Bogenbai Batyr str., Almaty, Kazakhstan; Bes Saiman Group, 38, Tulebayeva str., Almaty, Kazakhstan https://orcid.org/0000-0002-4588-1521

DOI:

https://doi.org/10.18321/cpc23(2)137-151

Keywords:

biomass waste, wheat straw, barley straw, rice husk, graphene-like structures, microwave action

Abstract

The article presents the results of studying the process of increasing the degree of graphitization and the yield of graphene-like structures (GLS) from pre-carbonized and activated biomass (wheat and barley straw, rice husk) by heating in a microwave oven. Microwave heating has significant advantages over conventional electric heating, which is more energy-intensive and often ineffective. Microwave heating is a convenient, economical and environmentally friendly way to obtain graphene, unlike complex multi-stage processes associated with the use of various chemical reagents. Using microwave heating, it is also possible to simplify the stage of graphene oxide reduction, since, due to the properties of graphene oxide to absorb microwaves, microwave irradiation can reduce it directly into graphene without any reducing agent or atmosphere. It is shown that the method of microwave temperature action on the HPS obtained from biomass leads to the removal of oxygen from 9-14% (in the original samples) to 0-4% when processed in a microwave oven at different temperatures, which significantly increases the degree of graphitization and the percentage of GLS yield and can be used to obtain a volumetric yield of the product for commercial purposes.

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