Влияние времени механохимической активации на формирование Fe-Co-MOF и оценка его каталитического воздействия при термическом разложении композиций AP/Al
DOI:
https://doi.org/10.18321/cpc24(3)361-370Ключевые слова:
механохимический синтез, время активации, металлорганические каркасные структуры, Fe–Co–MOF, термическое разложениеАннотация
В работе исследован механохимический синтез биметаллических металлорганических каркасных структур Fe-Co-MOF и влияние продолжительности активации на их структурные, морфологические и термические свойства. Синтез проводили методом механохимической активации при продолжительности обработки 1, 3 и 5 ч. Полученные материалы исследованы методами рентгенофазового анализа, ИК-Фурье-спектроскопии, сканирующей электронной микроскопии и дифференциальной сканирующей калориметрии. Результаты рентгенофазового анализа показали формирование Fe-Co-содержащей фазы с низкой степенью кристалличности. ИК-Фурье-спектроскопия подтвердила образование координационных связей между ионами металлов и органическим лигандом, а сканирующая электронная микроскопия выявила изменение морфологии от рыхлых агломератов к более плотным и упорядоченным структурам. Наиболее сформированная структура наблюдалась для образца Fe-Co-MOF(5). Исследование термического поведения композитных смесей AP/Al-Fe-Co-MOF методом дифференциальной сканирующей калориметрии показало, что введение Fe-Co-MOF ускоряет высокотемпературную стадию разложения и повышает интенсивность тепловых эффектов. Полученные результаты подтверждают перспективность применения Fe-Co-MOF в качестве каталитической добавки для регулирования термических характеристик энергетических композиций.
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Copyright (c) 2026 А.К. Абдрасилова, Д. Мукталы, К. Камунур, Л.А. Мусапирова, А.Н. Баткал, М.Т. Ыскак
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