Electrically conductive sealing silicone compositions filled with carbon materials
DOI:
https://doi.org/10.18321/cpc20(4)349-357Keywords:
Electrically conductive sealing silicone compositions filled with carbon materialsAbstract
Electrically conductive sealants and coatings have been of great interest in recent years due to the development of electronics and technology. A lot of research is being conducted in this field to study the electrically conductive properties of composites filled with various carbon materials. However, there are not many studies where siloxanes are used as matrices. The purpose of this work was to obtain an inexpensive electrically conductive composite using a silicone matrix and carbon fillers: carbon black, graphite, coal. The best filler for an electrically conductive sealant was carbon black (30 wt.%) demonstrated electrical conductivity of 1.11×102 (Ohm×m)-1. However, an increase in the carbon black content in the matrix negatively affected the physical and mechanical properties, the conditional tensile strength decreased by 42%, the elongation at break by 37%. The resulting composite can be used as an electrically conductive sealing material, however, if necessary, improvements in physical and mechanical characteristics are preserved.
References
(1) Beaucarne G, Broek K, Chisleac B, Yud Y, Weid J, Zambovac A (2014) Energy Procedia. 55:444–450. https://doi.org/10.1016/j.egypro.2014.08.007
(2) Petrenya R, Toth C, Horvath A, Meszaros L (2022) Heliyon. 8:E10287. https://doi.org/10.1016/j.heliyon.2022.e10287
(3) Wang L, Shen A, Wang W, Yang J, He Z, Zhijie T (2022) Case Studies in Construction Materials. 17:01402. https://doi.org/10.1016/j.cscm.2022.e01402
(4) Li Q, Liu M, Zhong B, Zhang W, Jia Zh, Jia D (2022) Composites Communications. 34:101249. https://doi.org/10.1016/j.coco.2022.101249
(5) Yu Zh, Wang C, Zhang X, Dattatray A, Yongxian P, Shibao Zh (2022) Composites Communications. 29:101051. https://doi.org/10.1016/j.coco.2021.101051
(6) Shang S, Gan L, Chun-wah Yuen M, Jiang Sh, Mei Luo N (2014) Composites: Part A. 66:135–141. https://doi.org/10.1016/j.compositesa.2014.07.014
(7) Yang H, Yao X, Yuan L, Gong L, Liu Y (2019) Nanoscale. 11:578-86. https://doi.org/10.1039/C8NR07737A
(8) Lin Y, Liu S, Chen S, Wei Y, Dong X, Liu L (2016) J Mater Chem C. 4:6345-52. https://doi.org/10.1039/C6TC01925K
(9) Kumar V, Lee G, Singh K, Choi J, Lee D (2020) Sensors and Actuators A: Physical. 303:111712. https://doi.org/10.1016/j.sna.2019.111712
(10) Shashkeev KA, Nagornaya VS, Volkov IA, Kondrashov SV, Dyachkova TP, Kondakov AI (2017) Journal of Applied Chemistry [ZHurnal prikladnoj himii] 90(7):896-906. (in Russian) https://doi.org/10.1134/S1070427217070138
(11) Stolyarov RA, Memetova AE, Yakubov VS, Tkachev AG, Memetov NR (2022) Bulletin of the Tambov State Technical University [Vestnik Tambovskogo gosudarstvennogo tekhnicheskogo universiteta] 28(1):153-161. (in Russian) https://doi.org/10.17277/vestnik.2022.01.pp.153-161
(12) Burmistrov I, Gorshkov N, Ilinykh I, Muratov D, Kolesnikov E, Anshin S (2016) Composites Science and Technology 129:79-85. https://doi.org/10.1016/j.compscitech.2016.03.032
(13) Song P, Song J, Zhang Y (2020) Composites Part B: Engineering 191:107979. https://doi.org/10.1016/j.compositesb.2020.107979
(14) Galashina NM, Nedorezova PM, Shevchenko VG, Tsvetkova VI, Klyamkina AN, Chmutin IA (1993) High-molecular compounds [Vysokomolekulyarnye soedineniya] 35(8):1315-1319. (in Russian)
(15) Shchegolkov A.V., Yakubov V.S. Bulletin of Magnitogorsk State Technical University named after G.I. Nosov [Vestnik Magnitogorskogo gosudarstvennogo tekhnicheskogo universiteta im. G.I. Nosova] 18(1):40-48. (in Russian)
(16) Zyuzin AM, Karpeev AA, Yanzen NV, Naumkin VV (2020) Letters to the Housing Department [Pis’ma v ZHTF] 46:24. (in Russian)
(17) Stepashkina AS, Tsobkallo ES, Moskalyuk OA, Aleshin AN (2015) Letters to the Housing Department [Pis’ma v ZHTF] 41:2. (in Russian) https://doi.org/10.1134/S1063785015010307
(18) Ovsyannikov NYa, Kornev AE (2007) Vestnik MITKHT [Vestnik MITHT] 2(4):52. (in Russian)
(19) Gul VE, Shenfil LZ (1984) Electrically conductive polymer compositions [Elektroprovodyashchie polimernye kompozicii] Chemistry, Moscow, USSR. (in Russian)
(20) ASTM D 3849-04 (2007) Test Method for Carbon Black: Morphological Characterization of Carbon Black Using Electron Microscopy. Book of Standards. 9.
(21) Bansal RC (2005) Activated Сarbon Adsorption. Boca Raton: Taylor and Francis Group, CRC Press.
(22) Glazyrin AB, Abdullin MI, Basyrov AA, Koldaev NV, Koksharova YuA (2016) Bulletin of Bashkir University [Vestnik Bashkirskogo universiteta] 21:1. (in Russian)
(23) El-Tantawy F, Kamada K, Ohnabe H (2002) Materials Letters. 56:112-126. https://doi.org/10.1016/S0167-577X(02)00401-9